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We study the glass transition by exploring a broad class of kinetic rules that can significantly modify the normal dynamics of supercooled liquids while maintaining thermal equilibrium. Beyond the usual dynamics of liquids, this class includes dynamics in which a fraction (1-f_{R}) of the particles can perform pairwise exchange or "swap moves," while a fraction f_{P} of the particles can move only along restricted directions. We find that (i) the location of the glass transition varies greatly but smoothly as f_{P} and f_{R} change and (ii) it is governed by a linear combination of f_{P} and f_{R}. (iii) Dynamical heterogeneities (DHs) are not governed by the static structure of the material; their magnitude correlates instead with the relaxation time. (iv) We show that a recent theory for temporal growth of DHs based on thermal avalanches holds quantitatively throughout the (f_{R},f_{P}) diagram. These observations are negative items for some existing theories of the glass transition, particularly those reliant on growing thermodynamic order or locally favored structure, and open new avenues to test other approaches, as we illustrate.
RESUMO
Amorphous packings of nonspherical particles such as ellipsoids and spherocylinders are known to be hypostatic: The number of mechanical contacts between particles is smaller than the number of degrees of freedom, thus violating Maxwell's mechanical stability criterion. In this work, we propose a general theory of hypostatic amorphous packings and the associated jamming transition. First, we show that many systems fall into a same universality class. As an example, we explicitly map ellipsoids into a system of "breathing" particles. We show by using a marginal stability argument that in both cases jammed packings are hypostatic and that the critical exponents related to the contact number and the vibrational density of states are the same. Furthermore, we introduce a generalized perceptron model which can be solved analytically by the replica method. The analytical solution predicts critical exponents in the same hypostatic jamming universality class. Our analysis further reveals that the force and gap distributions of hypostatic jamming do not show power-law behavior, in marked contrast to the isostatic jamming of spherical particles. Finally, we confirm our theoretical predictions by numerical simulations.
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We study nonlocal effects associated with particle collisions in dense suspension flows, in the context of the Affine Solvent Model, known to capture various aspects of the jamming transition. We show that an individual collision changes significantly the velocity field on a characteristic volume Ω_{c}â¼1/δz that diverges as jamming is approached, where δz is the deficit in coordination number required to jam the system. Such an event also affects the contact forces between particles on that same volume Ω_{c}, but this change is modest in relative terms, of order f_{coll}â¼f[over ¯]^{0.8}, where f[over ¯] is the typical contact force scale. We then show that the requirement that coordination is stationary (such that a collision has a finite probability to open one contact elsewhere in the system) yields the scaling of the viscosity (or equivalently the viscous number) with coordination deficit δz. The same scaling result was derived [E. DeGiuli, G. Düring, E. Lerner, and M. Wyart, Phys. Rev. E 91, 062206 (2015)PLEEE81539-375510.1103/PhysRevE.91.062206] via different arguments making an additional assumption. The present approach gives a mechanistic justification as to why the correct finite size scaling volume behaves as 1/δz and can be used to recover a marginality condition known to characterize the distributions of contact forces and gaps in jammed packings.
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Dense non-Brownian suspension flows of hard particles display mystifying properties: As the jamming threshold is approached, the viscosity diverges, as well as a length scale that can be identified from velocity correlations. To unravel the microscopic mechanism governing dissipation and its connection to the observed correlation length, we develop an analogy between suspension flows and the rigidity transition occurring when floppy networks are pulled, a transition believed to be associated with the stress stiffening of certain gels. After deriving the critical properties near the rigidity transition, we show numerically that suspension flows lie close to it. We find that this proximity causes a decoupling between viscosity and the correlation length of velocities ξ, which scales as the length l(c) characterizing the response to a local perturbation, previously predicted to follow l(c)â¼ 1/sqrt[z(c)-z] â¼ p(0.18), where p is the dimensionless particle pressure, z is the coordination of the contact network made by the particles, and z(c) is twice the spatial dimension. We confirm these predictions numerically and predict the existence of a larger length scale l(r)â¼sqrt[p] with mild effects on velocity correlation and of a vanishing strain scale δγ â¼ 1/p that characterizes decorrelation in flow.
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We derive a microscopic criterion for the stability of hard sphere configurations and we show empirically that this criterion is marginally satisfied in the glass. This observation supports a geometric interpretation for the initial rapid rise in viscosity with packing fraction or previtrification. It also implies that barely stable soft modes characterize the glass structure, whose spatial extension is estimated. We show that both the short-term dynamics and activation processes occur mostly along those soft modes and we study some implications of these observations. This article synthesizes new and previous results [C. Brito and M. Wyart, Europhys. Lett. 76, 149 (2006); C. Brito and M. Wyart, J. Stat. Mech.: Theory Exp. 2007, L08003] in a unified view.