1.
Chempluschem
; : e202400380, 2024 Aug 13.
Artículo
en Inglés
| MEDLINE
| ID: mdl-39136597
RESUMEN
This article focuses on developing selective receptors for chloride. A series of novel receptors based on a rigid naphthalene spacer bearing tetrafluoropyridines (TFPs) in various substitution patterns has been designed and synthsized. The topology of the receptors was confirmed by X-ray cristallography. Their complexation efficiency was essentially studied in the gas phase through mass spectrometry experiments. Density Functional Theory (DFT) calculations and NMR titration were also performed.