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Cooperative Anion-π and C-H-Cl Interactions in Multifunctional Naphthalene-Based Receptors for Chloride Recognition: Cage-size Modulation Through Substitution Patterns.
Zayene, Olfa; Hu, Jun; Damond, Aurélie; Roc, Chantal; Marrot, Jérôme; Gaucher, Anne; Salpin, Jean-Yves; Prim, Damien.
Afiliación
  • Zayene O; Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, 45, Avenue des Etats-Unis, 78035, Versailles cedex, FRANCE.
  • Hu J; Université d'Evry-Val-d'Essonne, LAMBE, Boulevard François Mitterrand, 91025, Evry cedex, FRANCE.
  • Damond A; Université Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, 45, Avenue des Etats-Unis, 78035, Versailles cedex, FRANCE.
  • Roc C; Université d'Evry-Val-d'Essonne, LAMBE, Boulevard François Mitterrand, 91025, Evry cedex, FRANCE.
  • Marrot J; Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, 45, Avenue des Etats-Unis, 78035, Versailles cedex, FRANCE.
  • Gaucher A; Université Versailles Saint-Quentin-en-Yvelines, chemistry, 45, av. des Etats-Unis, 78035, VERSAILLES cedex, FRANCE.
  • Salpin JY; Université d'Évry-Val-d'Essonne, LAMBE, Boulevard François Mitterrand, 91025, Evry cedex, FRANCE.
  • Prim D; Université Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, 45, Avenue des Etats-Unis, 78035, Versailles cedex, FRANCE.
Chempluschem ; : e202400380, 2024 Aug 13.
Article en En | MEDLINE | ID: mdl-39136597
ABSTRACT
This article focuses on developing selective receptors for chloride. A series of novel receptors based on a rigid naphthalene spacer bearing tetrafluoropyridines (TFPs) in various substitution patterns has been designed and synthsized. The topology of the receptors was confirmed by X-ray cristallography. Their complexation efficiency was essentially studied in the gas phase through mass spectrometry experiments. Density Functional Theory (DFT) calculations and NMR titration were also performed.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chempluschem Año: 2024 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Alemania
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chempluschem Año: 2024 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Alemania