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Coffee Pulp Gasification for Syngas Obtention and Methane Production Simulation Using Ni Catalysts Supported on Al2O3 and ZrO2 in a Packed Bed Reactor.
Aristizábal-Alzate, Carlos Esteban; Dongil, Ana Belén; Romero-Sáez, Manuel.
Afiliação
  • Aristizábal-Alzate CE; Grupo Química Básica, Aplicada y Ambiente-Alquimia, Facultad de Ciencias Exactas y Aplicadas, Instituto Tecnológico Metropolitano-ITM, Medellín 050034, Colombia.
  • Dongil AB; Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, 28049 Madrid, Spain.
  • Romero-Sáez M; Grupo Química Básica, Aplicada y Ambiente-Alquimia, Facultad de Ciencias Exactas y Aplicadas, Instituto Tecnológico Metropolitano-ITM, Medellín 050034, Colombia.
Molecules ; 28(20)2023 Oct 11.
Article em En | MEDLINE | ID: mdl-37894505
The methanation of CO2 is of great interest in power-to-gas systems and contributes to the mitigation of climate change through carbon dioxide capture and the subsequent production of high-added-value products. This study investigated CO2 methanation with three Ni catalysts supported on Al2O3 and ZrO2, which were simulated using a mathematical model of a packed bed reactor designed based on their chemical kinetics reported in the literature. The simulated reactive system was fed with syngas obtained from residual coffee pulp obtained after a solvent phytochemical extraction process under several gasification conditions. The results reflect a high degree of influence of the catalyst support, preparation method, and syngas composition on CO2 and H2 conversions and CH4 selectivity. For all the syngas compositions, the Ni/ZrO2 catalysts showed the best values for CO2 conversion and H2 conversion for the Ni/Al2O3 catalyst except in gasification at 700 °C and using the Ni/ZrO2p catalyst.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Colômbia País de publicação: Suíça

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Colômbia País de publicação: Suíça