Cd2+ Detection by an Electrochemical Electrode Based on MWCNT-Orange Peel Activated Carbon.
ACS Omega
; 8(40): 37341-37352, 2023 Oct 10.
Article
em En
| MEDLINE
| ID: mdl-37841145
This study reports the development of a new electrochemical sensor based on a carbon paste electrode (CPE) composed of biomass-based orange peel activated carbon (ACOP) and multiwalled carbon nanotubes (MWCNTs), and this composite is used for the electrochemical detection of cadmium ions (Cd2+). The ACOP/MWCNT composite was characterized by FTIR, Raman, and electrochemical impedance spectroscopy. The electrochemical evaluation of Cd2+ was performed using square wave and cyclic voltammetry. The ACOP/MWCNT-CPE electrochemical sensor exhibited a coefficient of determination r2 of 0.9907, a limit of detection of 0.91 ± 0.79 µmol L-1, and a limit of quantification of 3.00 ± 2.60 µmol L-1. In addition, the developed sensor can selectively detect Cd2+ in the presence of different interferents such as Zn2+, Pb2+, Ni2+, Co2+, Cu2+, and Fe2+ with a relative standard deviation (RSD) close to 100%, carried out in triplicate experiments. The ACOP/MWCNT-CPE presented high sensitivity, stability, and reproducibility and was successfully applied for the detection of Cd2+ in river water samples with recovery rate values ranging from 97.33 to 115.6%, demonstrating to be a very promising analytical alternative for the determination of cadmium ions in this matrix.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Omega
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Peru
País de publicação:
Estados Unidos