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A New Approach to the Development of Hollow Fiber Membrane Modules for Water Treatment: Mixed Polymer Matrices.
da Silva Biron, Dionísio; Espíndola, Jonathan Cawettiere; Subtil, Eduardo Lucas; Mierzwa, José Carlos.
Afiliação
  • da Silva Biron D; International Reference Center on Water Reuse of the University of São Paulo (IRCWR-USP), Environmental and Hydraulic Department (PHA), Polytechnic School of the University of São Paulo (USP), São Paulo 05508-020, SP, Brazil.
  • Espíndola JC; International Reference Center on Water Reuse of the University of São Paulo (IRCWR-USP), Environmental and Hydraulic Department (PHA), Polytechnic School of the University of São Paulo (USP), São Paulo 05508-020, SP, Brazil.
  • Subtil EL; Laboratório de Tecnologias de Tratamento de Águas Urbanas Servidas e Reúso de Água (LabTAUS) of the Federal University of ABC, L005-Block L-Campus Santo André, São Paulo 09210-580, SP, Brazil.
  • Mierzwa JC; International Reference Center on Water Reuse of the University of São Paulo (IRCWR-USP), Environmental and Hydraulic Department (PHA), Polytechnic School of the University of São Paulo (USP), São Paulo 05508-020, SP, Brazil.
Membranes (Basel) ; 13(7)2023 Jun 21.
Article em En | MEDLINE | ID: mdl-37504979
In this study, mixed matrix hollow fiber polymeric membranes were prepared using polyethersulfone (PES) and polyvinylidene fluoride (PVDF) as polymers in their composition. N-methyl-2-pyrrolidone (NMP) was used as a solvent and demineralized water with an electrical conductivity below 3 µS·cm-1 was used as a non-solvent. A new approach to producing enhanced polymeric hollow fiber membranes based on the preparation of a simple blend PVDF/PES solution, and on the conformation of the composite membranes through the extrusion technique followed by the phase inversion process in a non-solvent bath, was applied. The investigation focused on the preparation of polymeric membranes with different polymer ratios and further assessment of the effects of these proportions on the membrane performance and in specific physical properties. The amount of PVDF ranged from 10 to 90% with 10% steps. The presence of PVDF, although it increased the membranes' plasticity, had a negative effect on the overall mechanical properties of the composite membranes. Scanning electron microscopy (SEM) results showed good dispersion of both polymers in the polymeric matrix. Furthermore, the membrane permeability showed a slight negative correlation with contact angle, suggesting that membrane hydrophilicity played an important role in membrane permeability. Finally, it was found that membranes with low ratios of PVDF/PES may have potential for water treatment applications, due to the combined advantageous properties of PES and PVDF.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Membranes (Basel) Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Brasil País de publicação: Suíça

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Membranes (Basel) Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Brasil País de publicação: Suíça