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Characterization and Modification of Red Mud and Ferrosilicomanganese Fines and Their Application in the Synthesis of Hybrid Hydrogels.
Ramírez, Arnaldo; Gómez, Leonir; Müller, Alejandro J; Rojas de Gáscue, Blanca.
Afiliação
  • Ramírez A; Laboratorio de Polímeros, Instituto de Investigaciones en Biomedicina y Ciencias Aplicadas, IIBCAUDO "Dra. Susan Tai", Universidad de Oriente, Cumaná 6101, Sucre, Venezuela.
  • Gómez L; Centro de Investigación de Materiales (CIMAT), Universidad Nacional de Guayana, Ciudad Guayana 8001, Bolívar, Venezuela.
  • Müller AJ; Grupo de Polímeros USB, Departamento de Ciencia de los Materiales, Universidad Simón Bolívar, Apartado 89000, Caracas 1080, Miranda, Venezuela.
  • Rojas de Gáscue B; POLYMAT and Department of Advanced Polymers and Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain.
Polymers (Basel) ; 14(20)2022 Oct 14.
Article em En | MEDLINE | ID: mdl-36297906
In this work, hybrid hydrogels were synthesized with the inclusion of two types of clay materials that are considered industrial waste: red mud (RM) and ferrosilicomanganese fines (FeSiMn). These solid waste materials were characterized by studying their particle size and chemical composition, which are two key variables for their application in the synthesis of hybrid hydrogels. The morphology imaged by transmission electron microscopy (TEM) and scanning electron microscopy (SEM), showed, in the case of RM, heterogeneous size and shape particles, with 73% of the particles having lengths of less than 5 µm. On the other hand, FeSiMn had particles with a circular morphology of nanometric sizes. Regarding the synthesis of the hybrid hydrogels, it was determined that the incorporation of small percentages (0.1%) of the inorganic phases improved the capacity of the materials to absorb water (swelling indices of 1678% and 1597% for the RM and FeSiMn hydrogels, respectively) compared to the conventional polyacrylamide hydrogel (1119%). An improvement in Vickers microhardness and storage modulus (G') was also observed: the hybrid with 10% RM presented a G', 50 times higher than conventional hydrogel. The results show the merit of RM and FeSiMn in improving the properties of hydrogels.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Polymers (Basel) Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Venezuela País de publicação: Suíça

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Polymers (Basel) Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Venezuela País de publicação: Suíça