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Affordable equipment to fabricate laser-induced graphene electrodes for portable electrochemical sensing.
Costa, Waleska R P; Rocha, Raquel G; de Faria, Lucas V; Matias, Tiago A; Ramos, David L O; Dias, Alessandro G C; Fernandes, Guilherme L; Richter, Eduardo M; Muñoz, Rodrigo A A.
Afiliação
  • Costa WRP; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Rocha RG; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • de Faria LV; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Matias TA; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Ramos DLO; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Dias AGC; Institute of Physics, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Fernandes GL; Institute of Physics, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Richter EM; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
  • Muñoz RAA; Center for Research On Electroanalysis, Institute of Chemistry, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil. munoz@ufu.br.
Mikrochim Acta ; 189(5): 185, 2022 04 09.
Article em En | MEDLINE | ID: mdl-35396635
Graphene-based materials present unique properties for electrochemical applications, and laser-induced conversion of polyimide to graphene is an emerging route to obtain a high-quality material for sensing. Herein we present compact and low-cost equipment constructed from an open-source 3D printer at which a 3.5-W visible (449 nm) laser was adapted to fabricate laser-induced graphene (LIG) electrodes from commercial polyimide, which resulted in electron transfer kinetic (k0) of 5.6 × 10-3 cm s-1 and reproducibility calculated by relative standard deviation (RSD < 5%) from cyclic voltammograms of [Fe(CN)6]3-/4- using 5 different electrodes. LIG electrodes enabled the simultaneous voltammetric determination of uric acid (+ 0.1 V vs. pseudo-reference) and nitrite (+ 0.4 V vs pseudo-reference), with limit of detection (LOD) values of 0.07 and 0.27 µmol L-1, respectively. Amperometric measurements for the detection of H2O2 (applying + 0.0 V vs. Ag|AgCl|KCl(sat.)) after Prussian blue (PB) modification and ciprofloxacin (applying + 1.2 V vs. Ag|AgCl|KCl(sat.)) were performed under flow conditions, which confirmed the high stability of LIG and LIG-PB surfaces. The LOD values were 1.0 and 0.2 µmol L-1 for H2O2 and ciprofloxacin, respectively. The RSD values (< 12%) obtained for the analysis using three different electrodes attested the precision of LIG electrodes manufactured in two designs. No sample matrix effects on the determination of ciprofloxacin in milk samples were observed  (recoveries between 84 and 96%). The equipment can be built with less than $300 and each LIG electrode costs less than $0.01.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Grafite Idioma: En Revista: Mikrochim Acta Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Brasil País de publicação: Áustria
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Grafite Idioma: En Revista: Mikrochim Acta Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Brasil País de publicação: Áustria