Your browser doesn't support javascript.
loading
Charge Storage and Solar Rechargeable Battery Devices Based on Electrodes Electrochemically Modified with Conducting Polymer Nanowires.
Ramírez, Andrés Mauricio; Gacitúa, Manuel Alejandro; Díaz, Fernando Raúl; Del Valle, María Angélica.
Afiliação
  • Ramírez AM; Laboratorio de Electroquímica y Materiales Aplicados, Centro de Nanotecnología Aplicada, Facultad de Ciencias, Universidad Mayor, Camino La Pirámide 5750, Santiago 8580745, Chile.
  • Gacitúa MA; Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L.B. O'Higgins 3363, Santiago 7254758, Chile.
  • Díaz FR; Laboratorio de Electroquímica de Polímeros, Pontificia Universidad Católica de Chile, Av. V. Mackenna 4860, Macul, Santiago 7820436, Chile.
  • Del Valle MA; Laboratorio de Electroquímica de Polímeros, Pontificia Universidad Católica de Chile, Av. V. Mackenna 4860, Macul, Santiago 7820436, Chile.
Polymers (Basel) ; 13(24)2021 Dec 14.
Article em En | MEDLINE | ID: mdl-34960927
In this work, the use of nanostructured conducting polymer deposits on energy-storing devices is described. The cathode and the anode are electrochemically modified with nanowires of polypyrrole and poly(3,4-ethylenedioxythiophene), respectively, prepared after the use of a mesoporous silica template. The effect of aqueous or ionic liquid medium is assayed during battery characterization studies. The nanostructured device greatly surpasses the performance of the bulk configuration in terms of specific capacity, energy, and power. Moreover, compared with devices found in the literature with similar designs, the nanostructured device prepared here shows better battery characteristics, including cyclability. Finally, considering the semi-conducting properties of the components, the device was adapted to the design of a solar-rechargeable device by the inclusion of a titanium oxide layer and cis-bis(isothiocyanate)-bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium (II) dye. The device proved that the nanostructured design is also appropriate for the implementation of solar-rechargeable battery, although its performance still requires further optimization.
Palavras-chave

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Polymers (Basel) Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Chile País de publicação: Suíça

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Polymers (Basel) Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Chile País de publicação: Suíça