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Fabrication of Multilayered Composite Nanofibers Using Continuous Chaotic Printing and Electrospinning: Chaotic Electrospinning.
Holmberg, Sunshine; Garza-Flores, Norma Alicia; Almajhadi, Mohammad Ali; Chávez-Madero, Carolina; Lujambio-Angeles, Alejandro; Jind, Binny; Bautista-Flores, Claudia; Mendoza-Buenrostro, Christian; Pérez-Carrillo, Esther; Wickramasinghe, Hemantha Kumar; Martínez-Chapa, Sergio Omar; Madou, Marc; Weiss, Paul S; Álvarez, Mario Moisés; Trujillo-de Santiago, Grissel.
Afiliação
  • Holmberg S; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Garza-Flores NA; Centro de Biotecnología-FEMSA, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Almajhadi MA; Department of Electrical Engineering and Computer Science, University of California, Irvine, Irvine, California 92697, United States.
  • Chávez-Madero C; Centro de Biotecnología-FEMSA, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Lujambio-Angeles A; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Jind B; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Bautista-Flores C; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Mendoza-Buenrostro C; Centro de Biotecnología-FEMSA, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Pérez-Carrillo E; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Wickramasinghe HK; Centro de Biotecnología-FEMSA, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Martínez-Chapa SO; Department of Electrical Engineering and Computer Science, University of California, Irvine, Irvine, California 92697, United States.
  • Madou M; Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico.
  • Weiss PS; Department of Mechanical and Aerospace Engineering, University of California, Irvine, Irvine, California 92697, United States.
  • Álvarez MM; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.
  • Trujillo-de Santiago G; Department of Bioengineering, University of California, Los Angeles, Los Angeles, California 90095, United States.
ACS Appl Mater Interfaces ; 13(31): 37455-37465, 2021 Aug 11.
Article em En | MEDLINE | ID: mdl-34339168
Multi-material and multilayered micro- and nanostructures are prominently featured in nature and engineering and are recognized by their remarkable properties. Unfortunately, the fabrication of micro- and nanostructured materials through conventional processes is challenging and costly. Herein, we introduce a high-throughput, continuous, and versatile strategy for the fabrication of polymer fibers with complex multilayered nanostructures. Chaotic electrospinning (ChE) is based on the coupling of continuous chaotic printing (CCP) and electrospinning, which produces fibers with an internal multi-material microstructure. When a CCP printhead is used as an electrospinning nozzle, the diameter of the fibers is further scaled down by 3 orders of magnitude while preserving their internal structure. ChE enables the use of various polymer inks for the creation of nanofibers with a customizable number of internal nanolayers. Our results showcase the versatility and tunability of ChE to fabricate multilayered structures at the nanoscale at high throughput. We apply ChE to the synthesis of unique carbon textile electrodes composed of nanofibers with striations carved into their surface at regular intervals. These striated carbon electrodes with high surface areas exhibit 3- to 4-fold increases in specific capacitance compared to regular carbon nanofibers; ChE holds great promise for the cost-effective fabrication of electrodes for supercapacitors and other applications.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Assunto da revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: México País de publicação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Assunto da revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: México País de publicação: Estados Unidos