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Effective treatment of hospital wastewater with high-concentration diclofenac and ibuprofen using a promising technology based on degradation reaction catalyzed by Fe0 under microwave irradiation.
Vieira, Yasmin; Pereira, Hércules A; Leichtweis, Jandira; Mistura, Clóvia M; Foletto, Edson L; Oliveira, Luis F S; Dotto, Guilherme L.
Afiliação
  • Vieira Y; Graduate Program in Chemistry, Federal University of Santa Maria, 97105-900 Santa Maria, Brazil.
  • Pereira HA; Graduate Program in Chemistry, Federal University of Santa Maria, 97105-900 Santa Maria, Brazil.
  • Leichtweis J; Graduate Program in Chemistry, Federal University of Santa Maria, 97105-900 Santa Maria, Brazil.
  • Mistura CM; Institute of Exact Sciences and Geosciences, University of Passo Fundo, BR 285, 99052-900 Passo Fundo, Brazil. Electronic address: clovia@upf.br.
  • Foletto EL; Graduate Program in Chemical Engineering, Federal University of Santa Maria, 97105-900, Brazil.
  • Oliveira LFS; Universidad de la Costa, Department of Civil and Environmental Engineering, Barranquilla, Colombia. Electronic address: lsilva8@cuc.edu.co.
  • Dotto GL; Graduate Program in Chemistry, Federal University of Santa Maria, 97105-900 Santa Maria, Brazil; Graduate Program in Chemical Engineering, Federal University of Santa Maria, 97105-900, Brazil. Electronic address: guilherme.dotto@ufsm.br.
Sci Total Environ ; 783: 146991, 2021 Aug 20.
Article em En | MEDLINE | ID: mdl-33865131
Real hospital wastewater was effectively treated by a promising technology based on degradation reaction catalyzed by Fe0 under microwave irradiation in this work. Fe0 powders were synthesized and characterized by different techniques, resulting in a single-phase sample with spherical particles. Optimum experimental conditions were determined by a central composite rotatable design combined with a response surface methodology, resulting in 96.8% of chemical oxygen demand reduction and 100% organic carbon removal, after applying MW power of 780 W and Fe0 dosage of 0.36 g L-1 for 60 min. Amongst the several organic compounds identified in the wastewater sample, diclofenac and ibuprofen were present in higher concentrations; therefore, they were set as target pollutants. Both compounds were completely degraded in 35 min of reaction time. Their plausible degradation pathways were investigated and proposed. Overall, the method developed in this work effectively removed high concentrations of pharmaceuticals in hospital wastewater.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Poluentes Químicos da Água / Águas Residuárias Idioma: En Revista: Sci Total Environ Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Brasil País de publicação: Holanda

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Poluentes Químicos da Água / Águas Residuárias Idioma: En Revista: Sci Total Environ Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Brasil País de publicação: Holanda