Monitoring chemical compositional changes of simulated spilled Brazilian oils under tropical climate conditions by multiple analytical techniques.
Mar Pollut Bull
; 164: 111985, 2021 Mar.
Article
em En
| MEDLINE
| ID: mdl-33482499
To comprehensively understand the chemical changes over time of spilled oils subject to tropical climate conditions and the active weathering processes, a spill simulation experiment was conducted along 210 days with two distinct Brazilian oils (19 and 24 API) under irradiation and non-irradiation of sunlight. Isoprenoids and n-alkanes showed a great loss after 40 days for both oils under the two conditions due to evaporation. Diagnostic ratios of saturated biomarkers showed no changes, whereas the polycyclic aromatic hydrocarbons had a decreasing concentration under both conditions mainly due to evaporation. Furthermore, oxygenated polar compounds produced by photooxidation were investigated by ESI(-) FT-ICR MS and showed changes only for the oils exposed to sunlight irradiation. Based on the observed polar compositional changes, new parameters are suggested using heteroatom classes to estimate oil spill time under tropical conditions: NO3/NO2; NO3/(NO + NO2); ∑NOx/N1; (O4 + O3)/(O2 + O1); O4/(O2 + O1); and O3/O2.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Hidrocarbonetos Policíclicos Aromáticos
/
Poluentes Químicos da Água
/
Petróleo
/
Poluição por Petróleo
País/Região como assunto:
America do sul
/
Brasil
Idioma:
En
Revista:
Mar Pollut Bull
Ano de publicação:
2021
Tipo de documento:
Article
País de publicação:
Reino Unido