Electrochemical Study of a Hybrid Polymethyl Methacrylate Coating using SiO2 Nanoparticles toward the Mitigation of the Corrosion in Marine Environments.
Materials (Basel)
; 12(19)2019 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-31581421
The demand for hydrophobic polymer-based protective coatings to impart high corrosion resistance has increased recently. The increase of the hydrophobicity in a hybrid coating is a new challenge, for that reason and in order to protect a metallic surface of oxidant agents, a poly (methyl methacrylate) (PMMA) coating with the addition of a different amount of silicon dioxide (SiO2) was developed. The hybrid coating was applied on a sample of stainless steel AISI 304 by the dip-coating method. The characterization of the coatings was determined by electrochemical impedance spectroscopy and with a scanning electrochemical microscopy. The best coatings were PMMA and PMMA + SiO2 0.01% that exhibits a real impedance in the Nyquist diagram of 760 and 427,800 MΩâ
cm2, respectively, and the modulus of the real impedance in the Bode diagram present values of 2.2 × 108 and 3.3 × 108 Ωâ
cm2. Moreover, the phase angle presents constant values around 75° to 85° and 85° for the PMMA and PMMA + SiO2 0.01%, respectively. Moreover, the values of the real resistance for the PMMA + SiO2 0.01% coating present values in the order of Mega-ohms despite the coating exhibits an artificial defect in their surface. The contact angle test showed that the hydrophobicity of the hybrid PMMA + SiO2 0.01% coating is higher than that of the pure PMMA coatings. The hybrid PMMA + SiO2 coatings developed in this work are a very interesting and promising area of study in order to develop efficient products to protect metallic surfaces from corrosion phenomenon.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Materials (Basel)
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
México
País de publicação:
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