Hydrothermal carbonization of acerola (Malphigia emarginata D.C.) wastes and its application as an adsorbent.
Waste Manag
; 95: 466-475, 2019 Jul 15.
Article
em En
| MEDLINE
| ID: mdl-31351633
Hydrothermal carbonization (HTC) is a promising technique for the improved management and better use of agro-industrial wastes. In this study, the effects of temperature, reaction time, biomass/water ratio, feed-water pH, and agitation speed on the HTC of acerola wastes were investigated. The effects of these independent variables on process yield and on the total oxygenated functional groups of hydrochars were quantified. The best process conditions were obtained using the desirability function and the chemical-morphological properties of the hydrochar produced in these optimal conditions were investigated. The total number of oxygenated functional groups were found to be higher than those described in the literature for similar biomasses. The effects of temperature, solution pH, initial dye concentration, and adsorbent dosage on the adsorption of methylene blue using the obtained hydrochar were also investigated and the conditions necessary for the maximum removal and adsorption capacity were determined. Adsorption isotherms and thermodynamic studies have shown that methylene blue adsorption on the obtained hydrochar is endothermic and spontaneous. Thus, the HTC of acerola wastes may be a sustainable technology for the modification of underutilized wastes and their application as adsorbents of environmental contaminants.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Purificação da Água
Idioma:
En
Revista:
Waste Manag
Assunto da revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
Brasil
País de publicação:
Estados Unidos