Bi-Microporous Metal-Organic Frameworks with Cubane [M4 (OH)4 ] (M=Ni, Co) Clusters and Pore-Space Partition for Electrocatalytic Methanol Oxidation Reaction.
Angew Chem Int Ed Engl
; 58(35): 12185-12189, 2019 Aug 26.
Article
em En
| MEDLINE
| ID: mdl-31286629
Embedding cubane [M4 (OH)4 ] (M=Ni, Co) clusters within the matrix of metal-organic frameworks (MOFs) is a strategy to develop materials with unprecedented synergistic properties. Herein, a new material type based on the pore-space partition of the cubic primitive minimal-surface net (MOF-14-type) has been realized. CTGU-15 made from the [Ni4 (OH)4 ] cluster not only has very high BET surface area (3537â
m2 g-1 ), but also exhibits bi-microporous features with well-defined micropores at 0.86â
nm and 1.51â
nm. Furthermore, CTGU-15 is stable even under high pH (0.1 m KOH), making it well suited for methanol oxidation in basic medium. The optimal hybrid catalyst KB&CTGU-15 (1:2) made from ketjen black (KB) and CTGU-15 exhibits an outstanding performance with a high mass specific peak current of 527â
mA mg-1 and excellent peak current density (29.8â
mA cm-2 ) at low potential (0.6â
V). The isostructural cobalt structure (CTGU-16) has also been synthesized, further expanding the application potential of this material type.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
País/Região como assunto:
Cuba
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
China
País de publicação:
Alemanha