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Enhancement of 1.5 µm fluorescence signal from Er3+ due to Yb3+ in yttrium silicate powders pumped at 975 and 808 nm.
Rakov, Nikifor; Maciel, Glauco S.
Afiliação
  • Rakov N; PG-Ciência dos Materiais, Universidade Federal do Vale do São Francisco, 48902-300 Juazeiro, BA, Brazil.
Methods Appl Fluoresc ; 7(1): 015003, 2018 Nov 02.
Article em En | MEDLINE | ID: mdl-30256766
The effect of the presence of ytterbium (Yb3+) on the near-infrared (NIR) emission profile of erbium (Er3+), more specifically the 4I13/2 â†’ 4I15/2 radiative transition around 1.5 µm, in yttrium silicate crystalline ceramic powders prepared by combustion synthesis was investigated under different NIR laser excitation wavelengths (λ = 808 and 975 nm). Enhancement of fluorescence around 1.5 µm due to the presence of Yb3+ was observed, which has potential use in medicine (NIR-III biological window) and optical communications (C-band transmission window). Two different excitation channels involving energy transfer between Er3+ and Yb3+ were studied: one involving the sensitization of Er3+ by Yb3+ (for λ = 975 nm laser light excitation) and the other involving direct excitation of Er3+ with Yb3+ acting as an energy reservoir (for λ = 808 nm laser light excitation). The energy transfer mechanisms of both processes are discussed in the text.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Methods Appl Fluoresc Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Brasil País de publicação: Reino Unido

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Methods Appl Fluoresc Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Brasil País de publicação: Reino Unido