C-S Bond Cleavage and C-C Coupling in Cyclopentadienylchromium Complexes To Give the First Dithiooxamide-Bridged and Doubly Dithiocarbamate-Bridged Double Cubanes: [Cp6 Cr8 S8 {(C(S)NEt2 )2 }] and [Cp6 Cr8 S8 (S2 CNEt2 )2 ].
Angew Chem Int Ed Engl
; 40(17): 3236-3239, 2001 Sep 03.
Article
em En
| MEDLINE
| ID: mdl-29712071
Thermolysis of the dithiocarbamate complex 1 led to the formation of the thiocarbenoid complex 2 and two double cubanes: 3, which has an intercubane Cr-Cr bond and a dithiooxamide ligand in the µ-η2 ,η4 bonding mode, and 4, which contains two dithiocarbamate ligands in the µ-η1 ,η2 bonding mode.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
País/Região como assunto:
Cuba
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2001
Tipo de documento:
Article
País de publicação:
Alemanha