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C-S Bond Cleavage and C-C Coupling in Cyclopentadienylchromium Complexes To Give the First Dithiooxamide-Bridged and Doubly Dithiocarbamate-Bridged Double Cubanes: [Cp6 Cr8 S8 {(C(S)NEt2 )2 }] and [Cp6 Cr8 S8 (S2 CNEt2 )2 ].
Goh, Lai Yoong; Weng, Zhiqiang; Leong, Weng Kee; Leung, Pak Hing.
Afiliação
  • Goh LY; Department of Chemistry, National University of Singapore Kent Ridge, Singapore 119260 (Singapore) Fax: (+65) 779-1691.
  • Weng Z; Department of Chemistry, National University of Singapore Kent Ridge, Singapore 119260 (Singapore) Fax: (+65) 779-1691.
  • Leong WK; Department of Chemistry, National University of Singapore Kent Ridge, Singapore 119260 (Singapore) Fax: (+65) 779-1691.
  • Leung PH; Department of Chemistry, National University of Singapore Kent Ridge, Singapore 119260 (Singapore) Fax: (+65) 779-1691.
Angew Chem Int Ed Engl ; 40(17): 3236-3239, 2001 Sep 03.
Article em En | MEDLINE | ID: mdl-29712071
Thermolysis of the dithiocarbamate complex 1 led to the formation of the thiocarbenoid complex 2 and two double cubanes: 3, which has an intercubane Cr-Cr bond and a dithiooxamide ligand in the µ-η2 ,η4 bonding mode, and 4, which contains two dithiocarbamate ligands in the µ-η1 ,η2 bonding mode.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE País/Região como assunto: Cuba Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2001 Tipo de documento: Article País de publicação: Alemanha
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE País/Região como assunto: Cuba Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2001 Tipo de documento: Article País de publicação: Alemanha