Removal of methyl orange by heterogeneous Fenton catalysts prepared using glycerol as green reducing agent.
Environ Technol
; 39(21): 2822-2833, 2018 Nov.
Article
em En
| MEDLINE
| ID: mdl-28797210
This study aims to prepare environmentally friendly iron catalysts supported on silica, using glycerol as green reducing and stabilizing agent, for application in heterogeneous Fenton degradation of the pollutant dye methyl orange (MO). The catalysts were characterized by X-ray powder diffraction, atomic absorption spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric analyses, Mössbauer and Fourier transform infrared spectroscopies, which revealed the formation of iron(II)/(III) oxalates from the oxidation of glycerol by the iron(III) nitrate precursor. Besides, iron oxihydroxide nanoparticles with superparamagnetic behavior were also formed. Iron catalysts prepared in the presence of nickel(II) or zinc(II) nitrates lead to the formation of the corresponding oxalates. The catalysts were able to degrade MO, efficiently in 180â
min of reaction. Fe/SiO2 furnished higher reaction rates, followed by Zn4Fe2/SiO2, which presented higher iron content as well as the smallest nanoparticles. Reaction parameters such as catalyst dosage, hydrogen peroxide concentration, pH and reaction temperature were investigated.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Substâncias Redutoras
/
Glicerol
Idioma:
En
Revista:
Environ Technol
Assunto da revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Brasil
País de publicação:
Reino Unido