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A new model for including the effect of fly ash on biochemical methane potential.
Gertner, Pablo; Huiliñir, César; Pinto-Villegas, Paula; Castillo, Alejandra; Montalvo, Silvio; Guerrero, Lorna.
Afiliação
  • Gertner P; Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago, Chile.
  • Huiliñir C; Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago, Chile. Electronic address: cesar.huilinir@usach.cl.
  • Pinto-Villegas P; Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago, Chile.
  • Castillo A; Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago, Chile.
  • Montalvo S; Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago, Chile.
  • Guerrero L; Departamento de Ingeniería Química y Ambiental, Universidad Técnica Federico Santa Maria, Valparaiso, Chile.
Waste Manag ; 68: 232-239, 2017 Oct.
Article em En | MEDLINE | ID: mdl-28697963
The modelling of the effect of trace elements on anaerobic digestion, and specifically the effect of fly ash, has been scarcely studied. Thus, the present work was aimed at the development of a new function that allows accumulated methane models to predict the effect of FA on the volume of methane accumulation. For this, purpose five fly ash concentrations (10, 25, 50, 250 and 500mg/L) using raw and pre-treated sewage sludge were used to calibrate the new function, while three fly ash concentrations were used (40, 150 and 350mg/L) for validation. Three models for accumulated methane volume (the modified Gompertz equation, the logistic function, and the transfer function) were evaluated. The results showed that methane production increased in the presence of FA when the sewage sludge was not pre-treated, while with pretreated sludge there is inhibition of methane production at FA concentrations higher than 50mg/L. In the calibration of the proposed function, it fits well with the experimental data under all the conditions, including the inhibition and stimulating zones, with the values of the parameters of the methane production models falling in the range of those reported in the literature. For validation experiments, the model succeeded in representing the behavior of new experiments in both the stimulating and inhibiting zones, with NRMSE and R2 ranging from 0.3577 to 0.03714 and 0.2209 to 0.9911, respectively. Thus, the proposed model is robust and valid for the studied conditions.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cinza de Carvão / Metano Tipo de estudo: Prognostic_studies Idioma: En Revista: Waste Manag Assunto da revista: SAUDE AMBIENTAL / TOXICOLOGIA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Chile País de publicação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cinza de Carvão / Metano Tipo de estudo: Prognostic_studies Idioma: En Revista: Waste Manag Assunto da revista: SAUDE AMBIENTAL / TOXICOLOGIA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Chile País de publicação: Estados Unidos