Mechanistic insights on the reactivity of furospirostanes with the 16ß,22:22,25-diepoxy-23-acetoxymethyl-24-methyl side chain.
Steroids
; 78(9): 787-97, 2013 Sep.
Article
em En
| MEDLINE
| ID: mdl-23707575
F-ring opening in spirostanes with the 16ß,22:22,25-diepoxy-23-acetoxymethyl-24-methyl side chain produces a Δ(22)-intermediate with an allylic acetoxy group. For this reason the reactivity profile of these compounds deviates from that observed in other naturally occurring or synthetic spirostanes and furospirostanes.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Espirostanos
/
Compostos de Epóxi
Idioma:
En
Revista:
Steroids
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
México
País de publicação:
Estados Unidos