Bis[(1RS,2RS)-4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium] tris-[tetra-chloridopalladate(II)].
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 1): m65-6, 2013 Jan 01.
Article
em En
| MEDLINE
| ID: mdl-23476356
The asymmetric unit of the title compound, (C12H16N3O)2[PdCl4]3, consists of a 4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium dication and one and a half tetra-chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza-niumyl-2-hy-droxy-ethane fragment show an anti conformation, as indicated by the central C-C-C-C torsion angle of -178.1â
(4)°, and they are inclined to one another by 25.7â
(2)°. In the crystal, the cations and anions are linked through N-Hâ¯Cl and O-Hâ¯Cl hydrogen bonds. There are also π-π contacts [centroid-centroid distance = 3.788â
(3)â
Å] and a number of C-Hâ¯O and C-Hâ¯Cl inter-actions are present, consolidating the formation of a three-dimensional structure.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
México
País de publicação:
Estados Unidos