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Bis[(1RS,2RS)-4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium] tris-[tetra-chloridopalladate(II)].
Campos-Gaxiola, Jose J; Baez-Castro, Alberto; Cruz-Enriquez, Adriana; Hopfl, Herbert; Parra-Hake, Miguel.
Afiliação
  • Campos-Gaxiola JJ; Facultad de Ingenieria Mochis, Universidad Autonoma de Sinaloa, Fuente Poseidon y Prol. A. Flores S/N, CP 81223, C.U. Los Mochis, Sinaloa, Mexico.
Acta Crystallogr Sect E Struct Rep Online ; 69(Pt 1): m65-6, 2013 Jan 01.
Article em En | MEDLINE | ID: mdl-23476356
The asymmetric unit of the title compound, (C12H16N3O)2[PdCl4]3, consists of a 4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium dication and one and a half tetra-chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza-niumyl-2-hy-droxy-ethane fragment show an anti conformation, as indicated by the central C-C-C-C torsion angle of -178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N-H⋯Cl and O-H⋯Cl hydrogen bonds. There are also π-π contacts [centroid-centroid distance = 3.788 (3) Å] and a number of C-H⋯O and C-H⋯Cl inter-actions are present, consolidating the formation of a three-dimensional structure.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2013 Tipo de documento: Article País de afiliação: México País de publicação: Estados Unidos
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2013 Tipo de documento: Article País de afiliação: México País de publicação: Estados Unidos