A new hybrid organic-inorganic chain: [(phen)Cu-µ-(κ2O:O'-VP2O10H3)2-Cu(phen)]n.
Acta Crystallogr C
; 68(Pt 7): m200-2, 2012 Jul.
Article
em En
| MEDLINE
| ID: mdl-22763689
The structure of the title compound, poly[(dihydrogenphosphato-κO)(µ(3)-hydrogenphosphato)di-µ-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO(4))(H(2)PO(4))O(2)(C(12)H(8)N(2))](n), is defined by [(phen)Cu-µ-(κ(2)O:O'-VP(2)O(10)H(3))(2)-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they interdigitate through the phen groups via π-π interactions.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr C
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Chile
País de publicação:
Estados Unidos