Heterodinuclear Fe(III)Zn(II)-bioinspired complex supported on 3-aminopropyl silica. Efficient hydrolysis of phosphate diester bonds.
Inorg Chem
; 49(6): 2580-2, 2010 Mar 15.
Article
em En
| MEDLINE
| ID: mdl-20163108
Presented herein is the synthesis and characterization of a new Fe(III)Zn(II) complex containing a Fe(III)-bound phenolate with a carbonyl functional group, which was anchored to 3-aminopropyl-functionalized silica as the solid support. The catalytic efficiency of the immobilized catalyst in the hydrolysis of 2,4-bis(dinitrophenyl)phosphate is comparable to the homogeneous reaction, and the supported catalyst can be reused for subsequent diester hydrolysis reactions.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Fosfatos
/
Compostos Férricos
/
Compostos de Zinco
/
Dióxido de Silício
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Brasil
País de publicação:
Estados Unidos