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Perfume fingerprinting by easy ambient sonic-spray ionization mass spectrometry: nearly instantaneous typification and counterfeit detection.
Haddad, Renato; Catharino, Rodrigo Ramos; Marques, Lygia Azevedo; Eberlin, Marcos Nogueira.
Afiliação
  • Haddad R; ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, State University of Campinas, 13084-971, Campinas SP, Brazil.
Rapid Commun Mass Spectrom ; 22(22): 3662-6, 2008 Nov.
Article em En | MEDLINE | ID: mdl-18946866
Perfume counterfeiting is an illegal worldwide practice that involves huge economic losses and potential consumer risk. EASI is a simple, easily performed and rapidly implemented desorption/ionization technique for ambient mass spectrometry (MS). Herein we demonstrate that EASI-MS allows nearly instantaneous perfume typification and counterfeit detection. Samples are simply sprayed onto a glass rod or paper surface and, after a few seconds of ambient drying, a profile of the most polar components of the perfume is acquired. These components provide unique and reproducible chemical signatures for authentic perfume samples. Counterfeiting is readily recognized since the exact set and relative proportions of the more polar chemicals, sometimes at low concentrations, are unknown or hard to reproduce by the counterfeiters and hence very distinct and variable EASI-MS profiles are observed for the counterfeit samples.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Perfumes / Espectrometria de Massas por Ionização por Electrospray Tipo de estudo: Diagnostic_studies / Evaluation_studies Idioma: En Revista: Rapid Commun Mass Spectrom Ano de publicação: 2008 Tipo de documento: Article País de afiliação: Brasil País de publicação: Reino Unido

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Perfumes / Espectrometria de Massas por Ionização por Electrospray Tipo de estudo: Diagnostic_studies / Evaluation_studies Idioma: En Revista: Rapid Commun Mass Spectrom Ano de publicação: 2008 Tipo de documento: Article País de afiliação: Brasil País de publicação: Reino Unido