Oxidative degradations of the side chain of unsaturated ent-labdanes. Part II.
Molecules
; 12(12): 2605-20, 2007 Dec 21.
Article
em En
| MEDLINE
| ID: mdl-18259147
A route for the degradation of the side chain of ent-labdane derivatives has been devised, giving the useful synthon 2beta,12-dihydroxy-13,14,15,16,17-pentanor-ent-labdane-8-one (8). The use of this compound in the preparation of terpenylquinone derivatives shall be reported elsewhere. In addition we have synthesized the compound 2beta,12-diacetoxy-8beta,17-epoxy-13,14,15,16-tetranor-ent-labdane (10), which upon catalytic epoxide ring opening in alkaline or acid media gave rise in all cases to the formation of tricyclicc ompounds.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Diterpenos
Idioma:
En
Revista:
Molecules
Assunto da revista:
BIOLOGIA
Ano de publicação:
2007
Tipo de documento:
Article
País de afiliação:
Chile
País de publicação:
Suíça