2,9-bis(3-nitrophenyl)-1-azaadamantan-4-one.

Jiménez-Cruz, F; Cetina-Rosado, R; Hernández-Ortega, S; Toscano, R A; Ríos-Olivares, H

Jiménez-Cruz, F; Cetina-Rosado, R; Hernández-Ortega, S; Toscano, R A; Ríos-Olivares, H.

Afiliação

Jiménez-Cruz F; Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán 04510, México DF, Mexico. fjimenez@servidor.unam.mx

Acta Crystallogr C ; 57(Pt 7): 868-9, 2001 Jul.

Article em En | MEDLINE | ID: mdl-11443270

RESUMO

The title compound, 2,9-bis(3-nitrophenyl)-1-azatricyclo[3.3.1.1(3,7)]decan-4-one, C21H19N3O5, has a tricyclic structure. The torsion angles may be used to describe the relationship of the carbonyl group to the adjacent faces, whereby it is seen that the angles on the face of the arylpiperidinone side [122.0 (3) and -122.0 (3) degrees ] are greater than those on the cyclohexanone side [-119.8 (4) and 119.9 (4) degrees ]. Although these differences may explain a facial selectivity during nucleophilic addition to the carbonyl group, the presence of the aryl rings is probably also important.

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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr C Ano de publicação: 2001 Tipo de documento: Article País de afiliação: México País de publicação: Estados Unidos

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