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L- and D-S-nitroso-beta,beta-dimethylcysteine differentially increase cGMP in cultured vascular smooth muscle cells.
Travis, M D; Stoll, L L; Bates, J N; Lewis, S J.
Afiliación
  • Travis MD; Department of Pharmacology, University of Iowa, Iowa City 52242-1109, USA.
Eur J Pharmacol ; 318(1): 47-53, 1996 Dec 27.
Article en En | MEDLINE | ID: mdl-9007512
We examined the effects of the L- and D-isomers of S-nitroso-beta,beta-dimethylcysteine (L- and D-S-nitrosopenicillamine, 10(-7)-10(-5) M) on the guanosine 3',5'-cyclic monophosphate (cGMP) content of cultured porcine aortic smooth muscle cells and the decomposition of these stereoisomers to nitric oxide (NO). L-S-nitrosopenicillamine was a more potent generator of cGMP than D-S-nitrosopenicillamine although both stereoisomers equally decomposed to NO. The 10(-7) M concentration of L- or D-S-nitrosopenicillamine did not generate detectable amounts of NO although 10(-7) M L-S-nitrosopenicillamine but not D-S-nitrosopenicillamine generated significant amounts of cGMP. This study shows that the stereoisomeric configuration of S-nitrosopenicillamine is an important factor in its biological potency. The data suggest that the extracellular or intracellular generation of NO is not the only mechanism by which this S-nitrosothiol generates cGMP in vascular smooth muscle.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Penicilamina / Músculo Liso Vascular / Compuestos Nitrosos Límite: Animals Idioma: En Revista: Eur J Pharmacol Año: 1996 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Países Bajos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Penicilamina / Músculo Liso Vascular / Compuestos Nitrosos Límite: Animals Idioma: En Revista: Eur J Pharmacol Año: 1996 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Países Bajos