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The interaction of Q analogs, particularly hydroxydecyl benzoquinone (idebenone), with the respiratory complexes of heart mitochondria.
Esposti, M D; Ngo, A; Ghelli, A; Benelli, B; Carelli, V; McLennan, H; Linnane, A W.
Afiliación
  • Esposti MD; Centre for Molecular Biology and Medicine, Monash University, Melbourne, Victoria, Australia.
Arch Biochem Biophys ; 330(2): 395-400, 1996 Jun 15.
Article en En | MEDLINE | ID: mdl-8660670
We have studied the interaction of idebenone (2,3-dimethoxy-5-methy-6-(10-hydroxy)decyl-1,4-benzoquinone) with the energy-conserving complexes of the respiratory chain in beef heart mitochondria and compared its energetic efficiency with that of other analogs of coenzyme Q. Idebenone is a very effective substrate for succinate:Q reductase and ubiquinol:cytochrome c reductase, but it is clearly a poor substrate for NADH:Q reductase (complex I). Indeed, idebenone is a strong inhibitor of both the redox and proton pumping activity of complex I, showing effects in part similar to those of coenzyme Q-2. However, the mechanism of idebenone interaction with complex I may be different from that of Q-2 because of its different sensitivity to inhibitors. The possible relevance of the present findings to the therapeutic use of idebenone is discussed.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Benzoquinonas / Ubiquinona / Mitocondrias Cardíacas Límite: Animals Idioma: En Revista: Arch Biochem Biophys Año: 1996 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Benzoquinonas / Ubiquinona / Mitocondrias Cardíacas Límite: Animals Idioma: En Revista: Arch Biochem Biophys Año: 1996 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos