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The mutagenicity of chemically synthesized metabolites of 16,17-dihydro-15H-cyclopenta[a]phenanthrene and its carcinogenic 11-methyl homologue.
Papaparaskeva-Petrides, C; Ioannides, C; Boyd, G W; Young, R J; Harvey, R G; Coombs, M M.
Afiliación
  • Papaparaskeva-Petrides C; Department of Chemistry, School of Biological Sciences, University of Surrey, Guildford, UK.
Mutagenesis ; 8(4): 307-10, 1993 Jul.
Article en En | MEDLINE | ID: mdl-8377648
Putative synthetic metabolites of the hydrocarbon 16,17-dihydro-15H-cyclopenta[a]phenanthrene and its carcinogenic 11-methyl analogue, namely trans-3,4-dihydroxy-3,4,16,17-tetrahydro-15H- cyclopenta[a]phenanthrene and its 11-methyl derivative, together with the four associated trans-3,4-dihydroxy-syn- and anti-1,2-epoxides, were assayed for mutagenicity in the Ames test with Salmonella typhimurium TA100 with and without microsomal activation. The hydrocarbons were weakly mutagenic and the 3,4-diols were more strongly so, but all required activation to express their mutagenic potential. All four diol-epoxides were much more potent mutagens, even in the absence of activation. This is in accord with the anticipated metabolic activation sequence: hydrocarbons-->3,4-diols-->3,4-diol-1,2-epoxides.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fenantrenos / Carcinógenos / Mutágenos Límite: Animals Idioma: En Revista: Mutagenesis Asunto de la revista: GENETICA MEDICA / SAUDE AMBIENTAL Año: 1993 Tipo del documento: Article Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fenantrenos / Carcinógenos / Mutágenos Límite: Animals Idioma: En Revista: Mutagenesis Asunto de la revista: GENETICA MEDICA / SAUDE AMBIENTAL Año: 1993 Tipo del documento: Article Pais de publicación: Reino Unido