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Association of branched nucleic acids.
Hudson, R H; Damha, M J.
Afiliación
  • Hudson RH; Department of Chemistry, University of Toronto, Mississauga, Canada.
Nucleic Acids Symp Ser ; (29): 97-9, 1993.
Article en En | MEDLINE | ID: mdl-8247812
Various branched nucleic acids (bNA's) of the general formula, 5'-(N)xrA[2'-(N)y], 3'-(N)y, have been prepared and their association with complementary linear oligonucleotides has been studied. The binding of complementary sequences to bNA's (for instance when N = dT, x = 0; y = 10 or x = y = 10 and the complement is dA10) yields transition temperatures (Tm's) equal to or greater than those of the corresponding linear complexes of similar base composition. Furthermore, a saturation of binding is observed when the number of mole-equivalents of complementary sequence equals the number of "arms" less one (n-1), i.e., for the "Y"-shaped molecule, 5'-T10-rA[(2'-T10), 3'-T10]; n = 3, saturation occurs at two equivalents of complementary sequence. The significance of these results is discussed in terms of possible triple helix formation.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ácidos Nucleicos / Conformación de Ácido Nucleico Tipo de estudio: Risk_factors_studies Idioma: En Revista: Nucleic Acids Symp Ser Año: 1993 Tipo del documento: Article País de afiliación: Canadá Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ácidos Nucleicos / Conformación de Ácido Nucleico Tipo de estudio: Risk_factors_studies Idioma: En Revista: Nucleic Acids Symp Ser Año: 1993 Tipo del documento: Article País de afiliación: Canadá Pais de publicación: Reino Unido