Treatability of odorous dioxanes/dioxolanes in source water: How does molecular flexibility and pre-oxidation affect odorant adsorption.
Water Res
; 266: 122364, 2024 Sep 01.
Article
en En
| MEDLINE
| ID: mdl-39276475
ABSTRACT
Odorous dioxanes and dioxolanes, a class of cyclic acetals often produced as byproducts in polyester resin manufacturing, are problematic in drinking water treatment due to their low odor thresholds and resistance to conventional treatment technology. Our research focuses on the removal of ten dioxane/dioxolane compounds through oxidation and adsorption processes, exploring the key molecular properties that govern the treatmentability. We discovered that both chlorination and permanganate oxidation were largely ineffective at degrading cyclic acetals, achieving less than 20% removal even at high applicable doses. Conversely, powdered activated carbon (PAC) adsorption proved to be a more effective method, with a removal of > 90% at a PAC dosage of 10 mg/L for seven out of ten compounds. The presence of natural organic matter (NOM) reduced PAC adsorbability for all odorants, but the deterioration level substantially varied and mostly affected by structural flexibility as indicated by the number of rotatable bonds. The results of both the experimental investigation and molecular simulation corroborated the hypothesis that more rotatable bonds (from one to three here) are indicative of greater structural flexibility, which in consequence determines the susceptibility of cyclic acetals to NOM competitive adsorption. Increased structural flexibility could facilitate greater entry into silt-like micropores or achieve preferential adsorption sites with more compatible morphology against NOM competition. When pre-oxidation (chlorination and permanganate oxidation) and adsorption were applied sequentially, additional low molecular weight NOM components produced by pre-oxidation resulted in intensified NOM competition and decreased odorant adsorbability. If this combination is inevitably required for algae and odorant control, it would be beneficial to utilize a wise screen for oxidants and a reduced oxidant dose (less than 2 mg/L) to mitigate the deterioration of odorant adsorption. This study elucidates the roles of structural flexibility in influencing the treatability of dioxanes and dioxolanes, extending beyond the solely well-established effects of hydrophobicity. It also presents rational practice guidelines for the combination of pre-oxidation and adsorption in addressing odor incidents associated with dioxane and dioxolane compounds.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Water Res
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Reino Unido