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Mechanochemical "Cage-on-MOF" Strategy for Enhancing Gas Adsorption and Separation through Aperture Matching.
Liang, Yu; Xie, Gongfu; Liu, Kang-Kai; Jin, Meng; Chen, Yuanyuan; Yang, Xiaoxin; Guan, Zong-Jie; Xing, Hang; Fang, Yu.
Afiliación
  • Liang Y; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Xie G; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Liu KK; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Jin M; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Chen Y; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Yang X; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Guan ZJ; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Xing H; Hunan University, Chemistry and Chemical Engineering, CHINA.
  • Fang Y; Hunan University, College of Chemistry and Chemical Engineering, No.2 Lushan Southroad, 410000, Changsha, CHINA.
Angew Chem Int Ed Engl ; : e202416884, 2024 Sep 14.
Article en En | MEDLINE | ID: mdl-39275956
ABSTRACT
Post-modification of porous materials with molecular modulators has emerged as a well-established strategy for improving gas adsorption and separation. However, a notable challenge lies in maintaining porosity and the limited applicability of the current method. In this study, we employed the mechanochemical "Cage-on-MOF" strategy, utilizing porous coordination cages (PCCs) with intrinsic pores and apertures as surface modulators to improve the gas adsorption and separation properties of the parent MOFs. We demonstrated the fast and facile preparation of 28 distinct MOF@PCC composites by combining 7 MOFs with 4 PCCs with varying aperture sizes and exposed functional groups through a mechanochemical reaction in 5 mins. Only the combinations of PCCs and MOFs with closely matched aperture sizes exhibited enhanced gas adsorption and separation performance. Specifically, MOF-808@PCC-4 exhibited a significantly increased C2H2 uptake (+64%) and a longer CO2/C2H2 separation retention time (+40%). MIL-101@PCC-4 achieved a substantial C2H2 adsorption capacity of 6.11 mmol/g. This work not only highlights the broad applicability of the mechanochemical "Cage-on-MOF" strategy for the functionalization of a wide range of MOFs but also establishes potential design principles for the development of hybrid porous materials with enhanced gas adsorption and separation capabilities, along with promising applications in catalysis and intracellular delivery.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania