Role of Minor Phase Morphology on Mechanical and Shape-Memory Properties of Polylactide/Bio-Polyamide Nanocomposite.
Polymers (Basel)
; 16(17)2024 Aug 26.
Article
en En
| MEDLINE
| ID: mdl-39274046
ABSTRACT
In situ-generated nanofibrillar polymer-polymer composites are excellent candidates for the production of polymer materials, with high mechanical and SME properties. Their special feature is the high degree of dispersion of the in situ-generated nanofibers and the ability to form entangled nanofiber structures with high aspect ratios through an end-to-end coalescence process, which makes it possible to effectively reinforce the polymer matrix and, in many cases, increase its ductility. The substantial interfacial area, created by the in situ formed fiber/matrix morphology, significantly strengthens the interfacial interactions, which are crucial for shape fixation and shape recovery. Using the polylactide/bio-polyamide (PLA/PA) system as an example, it is shown that in situ PA fibrillation improves the mechanical and shape-memory properties of PLA. The modulus of elasticity increases by a factor of 1.4, the elongation at break increases by a factor of 30, and the shape-strain/fixity ratio and shape recovery increase from 80.2 to 97.4% and from 15.5 to 94.0%, respectively. The morphology of the minor PA phase is crucial. The best result is achieved when a physically entangled nanofibrous network is formed.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Polymers (Basel)
Año:
2024
Tipo del documento:
Article
País de afiliación:
Ucrania
Pais de publicación:
Suiza