Feasibility of biomass-based flexible and transparent AuNPs-acetylcellulose membrane for multifarious surface-enhanced Raman spectroscopy detection.
Anal Chim Acta
; 1327: 343157, 2024 Oct 23.
Article
en En
| MEDLINE
| ID: mdl-39266062
ABSTRACT
BACKGROUND:
Lignocellulosic biomass-based derivatives coupled with surface-enhanced Raman spectroscopy (SERS) technology have emerged as an appealing and indispensable tool in food safety and environmental monitoring for rapidly detecting trace contaminants like pesticide residues. The membrane material, serving as a substrate, ensures both sampling flexibility and test accuracy by directing the diffusion-adsorption process of the molecules. However, the existing membrane substrates, critical for the practical application of SERS, suffer from issues such as costly, intricate fabrication procedures, or restricted detection capabilities.RESULTS:
Herein, we present a flexible, transparent, and biodegradable cellulose acetate membrane with gold nanoparticles (AuNPs) uniformly embedded, fabricated using a simple scraping method. This membrane achieved a limit of detection (LOD) of thiram pesticide in water at 10-8 g mL-1. The unique optical transparency of the substrates allowed for in-situ detection on surfaces, with an LOD of thiram reaching 30 ng cm-2.SIGNIFICANCE:
Furthermore, SERS substrates made from corn stover-derived cellulose acetate enable the detection of various contaminants, highlighting their cost-effectiveness and eco-friendliness because of the abundance and low environmental impact of the raw materials.Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Espectrometría Raman
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Celulosa
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Biomasa
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Nanopartículas del Metal
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Oro
Idioma:
En
Revista:
Anal Chim Acta
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Países Bajos