Green-light Hydrosilylation Photocatalysis with Platinum(II) Metalla-N-Heterocyclic Carbene Complexes.

Kashina, Maria V; Luzyanin, Konstantin V; Katlenok, Eugene A; Kinzhalov, Mikhail A

Green-light Hydrosilylation Photocatalysis with Platinum(II) Metalla-N-Heterocyclic Carbene Complexes.

Kashina, Maria V; Luzyanin, Konstantin V; Katlenok, Eugene A; Kinzhalov, Mikhail A.

Afiliación

Kashina MV; St. Peterburg University, Department of chemistry, RUSSIAN FEDERATION.
Luzyanin KV; University of Liverpool, Department of chemistry, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND.
Katlenok EA; St Petersburg State University, Department of chemistry, RUSSIAN FEDERATION.
Kinzhalov MA; St. Peterburg State University, Insttitution of Chemistry, 7/9, Universitetskaya nab., 199034, Ð Ð¾ÑÑÐ¸Ñ, 199034, Saint Petersburg, RUSSIAN FEDERATION.

Chemistry ; : e202403264, 2024 Sep 10.

Article en En | MEDLINE | ID: mdl-39252655

ABSTRACT

ABSTRACT

Platinum(II) metalla-N-heterocyclic carbene complexes featuring pyridyl heterocyclic moiety demonstrate remarkable catalytic efficiency in alkyne hydrosilylation under green light irradiation. The photocatalytic properties of complexes are rationalised by the photo-induced charge transfer occurring in extended condensed system identified with the help of various experimental (UV/vis and emission spectroscopy, cyclic voltammetry) and theoretical methods (DFT/TD-DFT, IFCT analysis).

Palabras clave

diaminocarbenes; green light; hydrosilylation; photocatalysis; platinum

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article Pais de publicación: Alemania

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