Understanding the variations in degradation pathways and generated by-products of antibiotics in modified TiO2 and ZnO photodegradation systems: A comprehensive review.
J Environ Manage
; 370: 122402, 2024 Sep 06.
Article
en En
| MEDLINE
| ID: mdl-39243651
ABSTRACT
This review examines various modification techniques, including metal doping, non-metal doping, multi doping, mixed doping, and the construction of heterojunction photocatalysts, for enhancing the performance of pure TiO2 and ZnO in the photodegradation of antibiotics. The study finds that mixed and multi doping approaches are more effective in improving photodegradation performance compared to single doping. Furthermore, the selection of suitable semiconductors for constructing heterojunction photocatalysts is crucial for achieving an efficient charge carrier separation. The environmental impacts, recent research, and real application of photocatalysis process have been discussed. The review also investigates the impact of operating parameters on the degradation pathways and the generation of by-products for different antibiotics. Additionally, the toxicity of the by-products resulting from the photodegradation of antibiotics using modified ZnO and TiO2 photocatalysts is explored, revealing that these by-products may exhibit higher toxicity than the original antibiotics. Consequently, to enable the widespread implementation of photodegradation systems, researchers should focus on optimizing degradation systems to control the conversion pathways of by-products, developing innovative photoreactors, and evaluating toxicity in real wastewater matrices.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Environ Manage
Año:
2024
Tipo del documento:
Article
País de afiliación:
Egipto
Pais de publicación:
Reino Unido