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A special coupling strategy: Cu2MoS4 as a large-sized co-catalyst for promoting photocatalytic hydrogen production performance.
Yang, Guang; Dou, Mingyu; Liu, Xiaojie; Yang, Hua; Duan, Xiaosen; Wang, Hengyi; Yang, Ruixin; Liu, Erkang; Han, Baochen; Yin, Xingliang; Kong, Lingqian; Li, Dacheng; Dou, Jianmin.
Afiliación
  • Yang G; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Dou M; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China. Electronic address: 1085288135@qq.com.
  • Liu X; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Yang H; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Duan X; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Wang H; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Yang R; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Liu E; Institute of Powder Metallurgy and Advanced Ceramics, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, PR China.
  • Han B; Hebei Key Laboratory of Material Near-Net Forming Technology, School of Material Science and Engineering, Hebei University of Science and Technology, 26 Yuxiang Street, Shijiazhuang 050018, PR China. Electronic address: hbchebust@163.com.
  • Yin X; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Kong L; Dongchang College, Liaocheng University, Liaocheng 252000, PR China.
  • Li D; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China.
  • Dou J; Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, PR China. Electronic address: dougroup@163.com.
J Colloid Interface Sci ; 678(Pt B): 134-142, 2025 Jan 15.
Article en En | MEDLINE | ID: mdl-39241444
ABSTRACT
The photocatalytic hydrogen production performance of semiconductor materials can be improved by co-catalyst modification. In most of the studies, the size of the co-catalyst is relatively small compared to the primary catalyst. However, in this study, we employed a novel strategy by synthesizing a relatively large-sized Cu2MoS4 as the co-catalyst and in situ loading smaller-sized Zn0.5Cd0.5S onto Cu2MoS4, verifying that Cu2MoS4 enhances the photocatalytic hydrogen production efficiency of Zn0.5Cd0.5S. It can be observed by scanning electron microscopy (SEM) that the lateral size of 2D Cu2MoS4 is at least 50 times larger than the Zn0.5Cd0.5S nanoparticle particle size. In addition, Density Functional Theory (DFT) calculations have demonstrated that the active site for hydrogen production in the composite is located in Cu2MoS4. The large-sized of Cu2MoS4 not only provides more active sites but also broadens the electron transport channel, which is conducive to promoting the transfer of photogenerated electrons from Zn0.5Cd0.5S. This work enriches the study of large-sized materials as co-catalyst and provides a strategy for the construction of composite catalysts.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2025 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2025 Tipo del documento: Article Pais de publicación: Estados Unidos