Aerophobic/Hydrophilic Nickel-Iron Sulfide Nanoarrays for Energy-Saving Hydrogen Production from Seawater Splitting Assisted by Sulfion Oxidation Reaction.
Inorg Chem
; 2024 Sep 06.
Article
en En
| MEDLINE
| ID: mdl-39240171
ABSTRACT
Electrolysis of infinite seawater is a promising and sustainable approach for clean hydrogen production. However, it remains a big challenge to accomplish corrosion-resistant and chlorine-free seawater electrolysis at low power input. Herein, the bimetallic nickel-iron sulfide-based electrocatalytic nanoarrays are constructed by a facile hydrothermal sulfidation of redox-etched iron foam (IF), which manifests an effective and reliable strategy for the sulfion oxidation reaction (SOR) to assist alkaline seawater electrolysis for the achievement of energy-saving hydrogen production and value-added sulfion upcycling. The resulting NiFeSx/FeNi3/IF required 0.353 and 0.415 V vs RHE for SOR at current densities of 50 and 100 mA cm-2, which are considerably lower than the theoretical potential of the oxygen evolution reaction (OER, 1.23 V vs RHE). In situ spectroscopy analysis demonstrated efficient sulfion oxidation on the surface of NiFeSx/FeNi3/IF. Furthermore, the NiFeSx/FeNi3/IF-assembled electrolyzer delivered a greatly reduced cell voltage of 0.92 V at 50 mA cm-2 and maintains excellent durability for 30 h, achieving high Faradaic efficiency for both hydrogen production and sulfion degradation. In addition, under natural sunlight (660.4 W m-2), only a 0.947 V voltage of the solar panel smoothly powers the SOR-coupled seawater electrolysis for green hydrogen production and economic sulfur recovery.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Estados Unidos