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Chitosan-amidated lignin aerogel beads efficiently loaded with lanthanum hydroxide for phosphate removal from aqueous solutions.
Cui, Rui; Ma, Jiliang; Li, Xinze; Zhang, Junqiang; Liu, Zhendong; Zhang, Jia; Sun, Runcang.
Afiliación
  • Cui R; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
  • Ma J; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China. Electronic address: jlma@dlpu.edu.cn.
  • Li X; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
  • Zhang J; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
  • Liu Z; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
  • Zhang J; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
  • Sun R; Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China. Electronic address: rcsun3@dlpu.edu.cn.
Int J Biol Macromol ; 279(Pt 3): 135319, 2024 Nov.
Article en En | MEDLINE | ID: mdl-39236951
ABSTRACT
Developing phosphorus removal adsorbents with high adsorption performance and excellent structural stability remains a challenge. Herein, a chitosan (CS) - amidated lignin (AL) gel-bead adsorbent with high efficiency in immobilizing lanthanum hydroxide (La(OH)3) was fabricated via an in situ precipitation and freeze-drying strategy (abbreviated as La@ALCSx). The abundant hydroxyl and amino groups in CS promoted excellent loading of La(OH)3 on the surface and inside of the adsorbent. The introduction of lignin enhanced the structural stability of the beads along with the mass transfer efficiency. Owing to the porous structure and high La utilization, the adsorption capacity of La@ALCS2 reached 130.52 mg P g-1. Intra-sphere complexation of La(OH)3 with phosphate resulted in high adsorption selectivity of La@ALCS2. Moreover, the millimeter-sized of La@ALCS2 has favourable recoverability and maintains high adsorption performance after five adsorption-desorption cycles. Characterization analysis indicated that electrostatic attraction and ligand exchange were the main adsorption mechanisms. The excellent phosphorus removal efficiency, separation efficiency and recyclability of La@ALCSx provide a viable solution for the remediation of phosphate contaminated waters.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfatos / Contaminantes Químicos del Agua / Purificación del Agua / Quitosano / Lantano / Lignina Idioma: En Revista: Int J Biol Macromol Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Países Bajos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfatos / Contaminantes Químicos del Agua / Purificación del Agua / Quitosano / Lantano / Lignina Idioma: En Revista: Int J Biol Macromol Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Países Bajos