Defunctionalization Enabled by Intramolecular Radical Aromatic <i>Ipso</i> Substitution.

Zhang, Qijing; Liu, Tinglan; Wu, Lili; Zhou, Cong-Ying; Wang, Chengming

Defunctionalization Enabled by Intramolecular Radical Aromatic Ipso Substitution.

Zhang, Qijing; Liu, Tinglan; Wu, Lili; Zhou, Cong-Ying; Wang, Chengming.

Afiliación

Zhang Q; College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.
Liu T; College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.
Wu L; College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.
Zhou CY; College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.
Wang C; College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.

Org Lett ; 26(36): 7744-7750, 2024 Sep 13.

Article en En | MEDLINE | ID: mdl-39235307

ABSTRACT

ABSTRACT

A chemoselective and regioselective copper-promoted defunctionalization procedure has been developed, enabling the rapid construction of various N-polyheterocycles. Initial mechanistic studies reveal that a single-electron transfer radical process is potentially involved.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

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