Sn4+ Alloying and Chiral Incorporation into Tellurium Halides Triggering Tunable Luminescence Emission and Second-Harmonic Generation.
Inorg Chem
; 63(38): 17367-17371, 2024 Sep 23.
Article
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| MEDLINE
| ID: mdl-39229960
ABSTRACT
Recently, chiral organic-inorganic hybrid metal halides have attracted considerable interest as promising multifunctional materials, benefiting from their diverse structures and tunable photophysical properties. Herein, by introducing the chiral ligand methylbenzylamine (R-/S-MBA) and alloying Sn4+ cation, a series of tellurium-based halides R-/S-MBA2SnxTe1-xCl6 (x = 0, 0.125, 0.2, 0.365 and 0.54) with second-harmonic generation (SHG) effect and photoluminescence (PL) properties are successfully synthesized. Their optical bandgaps are determined to be 2.48-2.6 eV. Specifically, the introduction of chiral organic cations could break the structural symmetry and cause the tellurium halide to crystallize in the chiral space group. The incorporation of isovalent Sn4+ into the chiral host tellurium halides results in the increase in octahedral distortion, thereby promoting host intrinsic self-trapped emission that originates from the interconfigurational 3P0,1 â 1S0 transitions of Te4+. Consequently, the as-prepared Sn4+ doped halides, R-/S-MBA2SnxTe1-xCl6 (x = 0.365, 0.54), exhibit not only SHG response but also bright orange fluorescence. This study provides an effective strategy for designing chiral multifunctional materials.
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01-internacional
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MEDLINE
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En
Revista:
Inorg Chem
Año:
2024
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Article
Pais de publicación:
Estados Unidos