Janus nanocellulose membrane by nitrogen plasma: Hydrophilicity to hydrophobicity selective switch.
Carbohydr Polym
; 345: 122558, 2024 Dec 01.
Article
en En
| MEDLINE
| ID: mdl-39227097
ABSTRACT
Cellulose nanofibrils are one of the keystone materials for sustainable future, yet their poor water repellency hinders their push into industrial applications. Due to complexity and poor economical outcome and/or processing toxicity of the existing hydrophobization methods, nanocellulose loses against its antagonist plastic in medical and food industries. Herein, we demonstrate for the first time the "one-side selective water-repellency activation" in nanocellulose membranes by the means of mild N2-plasma treatment, exhibiting lowest wettability after 20 s of treatment. Hydrophobicity and accompanying Janus character were justified by the topological, chemical and structural reorganizations in cellulose nanofibrils. The findings suggest that the mechanism behind the hydrophilic/hydrophobic change primarily relies on the interplay between OH removal and appearance of SiCH3, originating from the polysiloxanes-based substrate, as well as complementary CNH2 groups formation. First-principles calculations show that NH2 groups moderately increase hydrophobicity, while various SiCH3 substitutions wholly change the character of the surface to repel water. Using nitrogen is shown to be crucial, as N(H)Si(CH3)3 groups induce greater hydrophobicity than simple OSi(CH3)3. Finally, the obtained materials absorb water on the hydrophilic side, while remaining hydrophobic on the other, exhibit high tensile strength, and protection against UV light, demonstrating applicability over wide range of applications.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Carbohydr Polym
Año:
2024
Tipo del documento:
Article
Pais de publicación:
Reino Unido