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Dramatically Enhancing Multiphoton Harvesting Metal-Organic Frameworks for NIR-II Photocatalysis through Functional Regulation of Octupolar Molecules.
Zhang, Luling; Li, Bo; Duan, Wenyao; Sun, Xianshun; Kai, Yuanzhong; Zhou, Hongping; Tian, Yupeng; Li, Dandan.
Afiliación
  • Zhang L; Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Ministry of Education, Anhui University, Hefei 230601, P. R. China.
  • Li B; Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Ministry of Education, Anhui University, Hefei 230601, P. R. China.
  • Duan W; Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Ministry of Education, Anhui University, Hefei 230601, P. R. China.
  • Sun X; School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, P. R. China.
  • Kai Y; School of Life Sciences, Anhui University, Hefei 230601, P. R. China.
  • Zhou H; School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, P. R. China.
  • Tian Y; School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, P. R. China.
  • Li D; Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Ministry of Education, Anhui University, Hefei 230601, P. R. China.
ACS Appl Mater Interfaces ; 16(36): 47348-47356, 2024 Sep 11.
Article en En | MEDLINE | ID: mdl-39223076
ABSTRACT
The development of effective multiphoton absorption (MPA) materials for near-infrared (NIR) light-driven photocatalysis holds great significance. In this study, we incorporated two multibranched cyclometallated iridium(III) modules with varying degrees of conjugation onto MPA-inert metal-organic frameworks (MOFs) to active MPA performance. Subsequently, the MOFs were further modified with Co(II) and hyaluronic acid (HA) to fabricate MINCH and MISCH, respectively. By introducing octupolar molecules and expanding the conjugation, MISCH exhibited a larger MPA cross section for efficient NIR light absorption and improved carrier transfer, leading to outstanding NIR light-driven multiphoton photocatalytic hydrogen production. Moreover, the HA modification enabled MISCH to achieve specific multiphoton photocatalytic hydrogen therapy for cancer cells. This study provides valuable insights into constructing highly active MPA materials for NIR light-driven photocatalysis, presenting a potential platform for hydrogen therapy in tumor treatment.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos