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Highly Selective Synthesis of Acetic Acid from Hydroxyl-Mediated Oxidation of Methane at Low Temperatures.
Wu, Bo; Yin, Haibin; Ma, Xinlong; Liu, Rongjia; He, Bingxuan; Li, Hongliang; Zeng, Jie.
Afiliación
  • Wu B; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • Yin H; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • Ma X; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • Liu R; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • He B; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • Li H; University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, CHINA.
  • Zeng J; USTC: University of Science and Technology of China, Hefei National Research Center for Physical Sciences at the Microscale, 96 Jinzhai Road, 230026, Hefei, CHINA.
Angew Chem Int Ed Engl ; : e202412995, 2024 Sep 02.
Article en En | MEDLINE | ID: mdl-39222321
ABSTRACT
Direct methane conversion and, in particular, the aerobic oxidation to acetic acid, remain an eminent challenge. Here, we reported a zeolite-supported Au-Fe catalyst (Au-Fe/ZSM-5) that converted methane to acetic acid with molecular oxygen as an oxidant in the presence of CO. Specifically, Au nanoparticles catalyzed the formation of hydroxyl species from the reaction of CO, O2, and H2O, meanwhile ZSM-5-supported atomically dispersed Fe species were responsible for the hydroxyl-mediated coupling of CH4 and CO to generate acetic acid. The reaction over 50 mg of Au-Fe/ZSM-5 under 62 bar (CH4 CO O2 = 14 14 3) at 120 °C for 3.0 h yielded 5.7 millimoles of acetic acid per gram of the catalyst (mmol gcat-1) with the selectivity of 92%, outperformed most of reported catalysts. Significantly, the catalyst remained active even at 60 °C. We anticipate that this hydroxyl-mediated route may guide the design of optimized catalysts for the direct methane functionalization at low temperatures.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania