Your browser doesn't support javascript.
loading
Accelerating catalytic conversion and chemisorption of polysulfides for advanced Li-S batteries from incorporating Fe0.64Ni0.36@Co5.47N hetero-nanocrystals into boron carbonitride nanotubes.
Guo, Xincheng; Wan, Pengfei; Xia, Peng; Jin, Xuanyang; Lu, Shengjun; Zhang, Yufei; Fan, Haosen.
Afiliación
  • Guo X; College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang 550025, China.
  • Wan P; College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang 550025, China.
  • Xia P; College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang 550025, China; School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China.
  • Jin X; College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang 550025, China.
  • Lu S; College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang 550025, China. Electronic address: sjlu@gzu.edu.cn.
  • Zhang Y; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China; Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China. Electronic address: yfzhang@gdut.edu.cn.
  • Fan H; School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China. Electronic address: hsfan@gzhu.edu.cn.
J Colloid Interface Sci ; 678(Pt A): 393-406, 2024 Aug 24.
Article en En | MEDLINE | ID: mdl-39213992
ABSTRACT
With the rapid development of large-scale clean energy, lithium-sulfur (Li-S) batteries are considered to be one of the most promising energy storage devices. In this manuscript, the polymetallic hetero-nanocrystal of iron nickel@cobalt nitride encapsulating into boron carbonitride nanotubes (Fe0.64Ni0.36@Co5.47N@BCN) was designed and optimized for use as a modified material for commercial polypropylene (PP) separators. The prepared Fe0.64Ni0.36@Co5.47N@BCN-12 hybrid material presents strong chemisorption and catalytic conversion capabilities, which endows the Fe0.64Ni0.36@Co5.47N@BCN-12//PP separator with enhanced polysulfide shuttling inhibition. The assembled Li-S cells with Fe0.64Ni0.36@Co5.47N@BCN-12//PP separators have minimized charge transfer resistance and faster redox kinetics. Additionally, cells with Fe0.64Ni0.36@Co5.47N@BCN-12//PP separator provide high reversible capacity of 674 mAh/g for 400 cycles at 0.5C and excellent cyclability for 1000 cycles at 2C with a low decay rate of 0.05 % per cycle. Therefore, this study provides a feasible functionalization route for improving the electrochemical performance of Li-S batteries through separator modification.
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos