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Changes in source contributions to the oxidative potential of PM2.5 in urban Xiamen, China.
Li, Jia-Min; Zhao, Si-Min; Miao, Qi-Yu; Wu, Shui-Ping; Zhang, Jie; Schwab, James J.
Afiliación
  • Li JM; Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Xiamen University, Xiamen 361102, China; Center for Marine Environmental Chemistry and Toxicology, College of Environment and Ecology, Xiamen University, Xiamen 361102, China.
  • Zhao SM; Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Xiamen University, Xiamen 361102, China; Center for Marine Environmental Chemistry and Toxicology, College of Environment and Ecology, Xiamen University, Xiamen 361102, China.
  • Miao QY; Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Xiamen University, Xiamen 361102, China; Center for Marine Environmental Chemistry and Toxicology, College of Environment and Ecology, Xiamen University, Xiamen 361102, China.
  • Wu SP; Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Xiamen University, Xiamen 361102, China; Center for Marine Environmental Chemistry and Toxicology, College of Environment and Ecology, Xiamen University, Xiamen 361102, China. Electronic address: wsp@xmu.edu.cn.
  • Zhang J; Atmospheric Sciences Research Center, University at Albany, SUNY, Albany 12226, USA.
  • Schwab JJ; Atmospheric Sciences Research Center, University at Albany, SUNY, Albany 12226, USA.
J Environ Sci (China) ; 149: 342-357, 2025 Mar.
Article en En | MEDLINE | ID: mdl-39181647
ABSTRACT
The toxicity of PM2.5 does not necessarily change synchronously with its mass concentration. In this study, the chemical composition (carbonaceous species, water-soluble ions, and metals) and oxidative potential (dithiothreitol assay, DTT) of PM2.5 were investigated in 2017/2018 and 2022 in Xiamen, China. The decrease rate of volume-normalized DTT (DTTv) (38%) was lower than that of PM2.5 (55%) between the two sampling periods. However, the mass-normalized DTT (DTTm) increased by 44%. Clear seasonal patterns with higher levels in winter were found for PM2.5, most chemical constituents and DTTv but not for DTTm. The large decrease in DTT activity (84%-92%) after the addition of EDTA suggested that water-soluble metals were the main contributors to DTT in Xiamen. The increased gap between the reconstructed and measured DTTv and the stronger correlations between the reconstructed/measured DTT ratio and carbonaceous species in 2022 were observed. The decrease rates of the hazard index (32.5%) and lifetime cancer risk (9.1%) differed from those of PM2.5 and DTTv due to their different main contributors. The PMF-MLR model showed that the contributions (nmol/(min·m3)) of vehicle emission, coal + biomass burning, ship emission and secondary aerosol to DTTv in 2022 decreased by 63.0%, 65.2%, 66.5%, and 22.2%, respectively, compared to those in 2017/2018, which was consistent with the emission reduction of vehicle exhaust and coal consumption, the adoption of low-sulfur fuel oil used on board ships and the reduced production of WSOC. However, the contributions of dust + sea salt and industrial emission increased.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Monitoreo del Ambiente / Contaminantes Atmosféricos / Material Particulado País/Región como asunto: Asia Idioma: En Revista: J Environ Sci (China) Asunto de la revista: SAUDE AMBIENTAL Año: 2025 Tipo del documento: Article País de afiliación: China Pais de publicación: Países Bajos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Monitoreo del Ambiente / Contaminantes Atmosféricos / Material Particulado País/Región como asunto: Asia Idioma: En Revista: J Environ Sci (China) Asunto de la revista: SAUDE AMBIENTAL Año: 2025 Tipo del documento: Article País de afiliación: China Pais de publicación: Países Bajos