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Hydrothermal extraction of ulvans from Ulva spp. in a biorefinery approach.
Rodríguez-Iglesias, Pablo; Baltrusch, Kai L; Díaz-Reinoso, Beatriz; López-Álvarez, Miriam; Novoa-Carballal, Ramón; González, Pío; González-Novoa, Alexandre; Rodríguez-Montes, Andrea; Kennes, Christian; Veiga, María C; Torres, María D; Domínguez, Herminia.
Afiliación
  • Rodríguez-Iglesias P; CINBIO, Universidade de Vigo, Departamento de Ingeniería Química, Campus Ourense, 32004 Ourense, Spain.
  • Baltrusch KL; CINBIO, Universidade de Vigo, Departamento de Ingeniería Química, Campus Ourense, 32004 Ourense, Spain.
  • Díaz-Reinoso B; CITI-University of Vigo, Parque Tecnolóxico de Galicia, Rúa Galicia n° 2, 32900 Ourense, Spain.
  • López-Álvarez M; CINTECX, Universidade de Vigo, Grupo de Novos Materiais, 36310 Vigo, Spain.
  • Novoa-Carballal R; CINBIO, Universidade de Vigo, Departamento de Química Orgánica, 36310 Vigo, Pontevedra, Spain.
  • González P; CINTECX, Universidade de Vigo, Grupo de Novos Materiais, 36310 Vigo, Spain.
  • González-Novoa A; Chemical Engineering Laboratory, Faculty of Sciences and Interdisciplinary Center for Chemistry and Biology (CICA), University of A Coruña, Rúa da Fraga, 10, 15008, Spain.
  • Rodríguez-Montes A; Chemical Engineering Laboratory, Faculty of Sciences and Interdisciplinary Center for Chemistry and Biology (CICA), University of A Coruña, Rúa da Fraga, 10, 15008, Spain.
  • Kennes C; Chemical Engineering Laboratory, Faculty of Sciences and Interdisciplinary Center for Chemistry and Biology (CICA), University of A Coruña, Rúa da Fraga, 10, 15008, Spain.
  • Veiga MC; Chemical Engineering Laboratory, Faculty of Sciences and Interdisciplinary Center for Chemistry and Biology (CICA), University of A Coruña, Rúa da Fraga, 10, 15008, Spain.
  • Torres MD; CINBIO, Universidade de Vigo, Departamento de Ingeniería Química, Campus Ourense, 32004 Ourense, Spain.
  • Domínguez H; CINBIO, Universidade de Vigo, Departamento de Ingeniería Química, Campus Ourense, 32004 Ourense, Spain. Electronic address: herminia@uvigo.es.
Sci Total Environ ; 951: 175654, 2024 Nov 15.
Article en En | MEDLINE | ID: mdl-39168316
ABSTRACT
A simple cascade process based on the hydrothermal fractionation of Ulva spp. biomass was proposed. Considering the overall extraction yields (50 %), ulvan recovery (23 %), and ulvan composition, structural, mechanical and cytotoxic properties, the selected optimal final heating temperature was 160 °C. Ethanol precipitation provided the highest ulvan recovery yields but choline chloride precipitated ulvans showed stronger mechanical properties, G´ moduli 1.5·104 Pa and 3·104 Pa for ethanol and for choline chloride, respectively. Both products were safe on NCTC 929 mouse fibroblasts and after a cooling stage, formed films without requiring any additives. From the ulvan-free liquid fraction, one product with 43 % (wt, d.b.) phenolics and moderate antiradical properties and a byproduct containing nutrients and minerals were separated. The methane potential of the corresponding residual solids was influenced by the hydrothermal heating temperature and was doubled compared to than for the untreated seaweed biomass (60 mL/g VS). This scheme could be also applied to the wet algal biomass, in a chemical free alternative to provide ready to use ulvan biopolymers, bioactives, nutrients, salts and biogas, conforming a biorefinery approach.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ulva Límite: Animals Idioma: En Revista: Sci Total Environ Año: 2024 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ulva Límite: Animals Idioma: En Revista: Sci Total Environ Año: 2024 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos