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Tunable temperature-responsive photonic ionogels with dual signals output.
Wu, Youtong; Li, Xueting; Tao, Jie; Zhang, Yuqi; Lu, Xihua.
Afiliación
  • Wu Y; College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China.
  • Li X; College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China; Fujian Nano-Micro Advanced Materials Sci. & Tech. Co. Ltd., Jinjiang Innovation Entrepreneurship and Creativity Park, Jinjiang, Fujian 362200, China; Shanghai Evanston Advanced Materials Sci. & Tech. C
  • Tao J; College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China.
  • Zhang Y; College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China.
  • Lu X; College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China; Fujian Nano-Micro Advanced Materials Sci. & Tech. Co. Ltd., Jinjiang Innovation Entrepreneurship and Creativity Park, Jinjiang, Fujian 362200, China; Shanghai Evanston Advanced Materials Sci. & Tech. C
J Colloid Interface Sci ; 677(Pt B): 704-718, 2025 Jan.
Article en En | MEDLINE | ID: mdl-39163665
ABSTRACT
Photonic ionogels with dual electrical and optical output have been intensively studied. However, tunable temperature-responsive photonic ionogel assembled by thermosensitive nanogels has not been studied yet. Herein, an innovative approach to fabricate photonic ionogels has been developed for smart wearable devices with tunable temperature sensitivity and structural color. Firstly, poly(isopropylacrylamide-r-phenylmaleanilic acid) P(NIPAm-r-NPMA) nanogels self-assemble into photonic crystals in 2-hydroxyethyl acrylate (HEA), water, and the ionic liquid of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate. And then robust photonic ionogels are developed through a polymerization of 2-hydroxyethyl acrylate crosslinked by poly(ethylene glycol) diacrylate (PEGDA). The incorporation of the ionic liquid, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate, enhances the mechanical strength of photonic ionogels and tunes the temperature-sensitivity of the ionogels, making them adaptable to various environmental conditions. The findings demonstrate that these ionogels can serve dual functions in smart wearable devices, combining electrical and optical signal outputs due to the conductivity of the ionic liquid and structural color from the nanogel assembly. The resultant photonic ionogels exhibit exceptional substrate adhesion, mechanical stability, and fast resilience. More significantly, the nanogels within these ionogels serve as the building blocks of photonic crystals (PCs) endow with angle-independent coloration and enhance stretchability beyond 200 %, while the stretchability of the ionogles without the nanogels is only about 100 %. Our photonic ionogels with tunable temperature-sensitivity and dual outputs will open an avenue to the development of the innovative smart wearable devices.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2025 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2025 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos