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Toward liquid cell quantum sensing: Ytterbium complexes with ultranarrow absorption.
Shin, Ashley J; Zhao, Changling; Shen, Yi; Dickerson, Claire E; Li, Barry; Roshandel, Hootan; Bím, Daniel; Atallah, Timothy L; Oyala, Paul H; He, Yongjia; Alson, Lianne K; Kerr, Tyler A; Alexandrova, Anastassia N; Diaconescu, Paula L; Campbell, Wesley C; Caram, Justin R.
Afiliación
  • Shin AJ; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Zhao C; Department of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Shen Y; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Dickerson CE; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Li B; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Roshandel H; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Bím D; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Atallah TL; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Oyala PH; Department of Chemistry and Biochemistry, Denison University, Granville, OH 43023, USA.
  • He Y; Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91103, USA.
  • Alson LK; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Kerr TA; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Alexandrova AN; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Diaconescu PL; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Campbell WC; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA.
  • Caram JR; Department of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA 90095, USA.
Science ; 385(6709): 651-656, 2024 Aug 09.
Article en En | MEDLINE | ID: mdl-39116250
ABSTRACT
The energetic disorder induced by fluctuating liquid environments acts in opposition to the precise control required for coherence-based sensing. Overcoming fluctuations requires a protected quantum subspace that only weakly interacts with the local environment. We report a ytterbium complex that exhibited an ultranarrow absorption linewidth in solution at room temperature with a full width at half maximum of 0.625 milli-electron volts. Using spectral hole burning, we measured an even narrower linewidth of 410 pico-electron volts at 77 kelvin. Narrow linewidths allowed low-field magnetic circular dichroism at room temperature, used to sense Earth-scale magnetic fields. These results demonstrated that ligand protection in lanthanide complexes could substantially diminish electronic state fluctuations. We have termed this system an "atomlike molecular sensor" (ALMS) and proposed approaches to improve its performance.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Science Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Science Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos