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Crystal structure of bis-[(η5-tert-butyl-cyclo-pentadien-yl)tri-carbonyl-molybdenum(I)](Mo-Mo).
Ibrahimova, Nigar Z; Tagiyev, Dilgam B; Lyatifov, Iltifat U; Akkurt, Mehmet; Hasanov, Khudayar I; Bhattarai, Ajaya.
Afiliación
  • Ibrahimova NZ; Acad. M. Nagiev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Azerbaijan Republic, Azerbaijan.
  • Tagiyev DB; Acad. M. Nagiev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Azerbaijan Republic, Azerbaijan.
  • Lyatifov IU; Acad. M. Nagiev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Azerbaijan Republic, Azerbaijan.
  • Akkurt M; Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Türkiye.
  • Hasanov KI; Western Caspian University, Istiqlaliyyat Street 31, AZ 1001, Baku, Azerbaijan.
  • Bhattarai A; Azerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14. AZ 1022, Baku, Azerbaijan.
Acta Crystallogr E Crystallogr Commun ; 80(Pt 8): 882-885, 2024 Aug 01.
Article en En | MEDLINE | ID: mdl-39108783
ABSTRACT
The dinuclear mol-ecule of the title compound, [Mo2(C9H13)2(CO)6] or [Mo( t BuCp)(CO)3]2 where t Bu and Cp are tert-butyl and cyclo-penta-dienyl, is centrosymmetric and is characterized by an Mo-Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, the t BuCp and the carbonyl ligands are in a transoid arrangement to each other. In the crystal, inter-molecular C-H⋯O contacts lead to the formation of layers parallel to the bc plane.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2024 Tipo del documento: Article País de afiliación: Azerbaiyán Pais de publicación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2024 Tipo del documento: Article País de afiliación: Azerbaiyán Pais de publicación: Reino Unido